Self assembly
We are looking at self-assembly using electrochemically and photochemically active ruthenium(II) building blocks. We do this by either self-assembling kinetically inert metal “building blocks” or using relatively labile ruthenium(II) centres as the “assembler.” The final multinuclear assemblies are being targeted as sensors for ions, molecules, and biomolecules, or can function as new paradigms for molecular devices.
A self-assembled Ru2Re2 luminescent sensor for ATP
A trinuclear Ru(II) anion receptor that functions as a ion-gated electron transfer switch